Structural, optical, and photoelectrochemical properties of nanosphere-like CdXZn1-XS synthesized by electrochemical route
Autor: | Vijay J. Fulari, Ninad B. Velhal, H. D. Dhaygude, Surendra Shinde, Dae-Young Kim, Deepak P. Dubal |
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Rok vydání: | 2016 |
Předmět: |
Micrograph
Nanostructure Materials science business.industry Band gap General Chemical Engineering General Engineering General Physics and Astronomy 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Tin oxide 01 natural sciences 0104 chemical sciences Field emission microscopy Optics Carbon film Chemical engineering General Materials Science Crystallite Thin film 0210 nano-technology business |
Zdroj: | Ionics. 23:223-231 |
ISSN: | 1862-0760 0947-7047 |
DOI: | 10.1007/s11581-016-1797-8 |
Popis: | Here, we present the effect of different Zn contents on the structural, morphological, and optical properties of CdXZn1-XS thin films deposited by electrodeposition method on stainless steel and indium-doped tin oxide (ITO) glass substrates. Electrosynthesized CdXZn1-XS thin films are characterized by using X-ray diffraction (XRD), UV-Vis spectrophotometer, field emission scanning electron microscope (FE-SEM), and surface wettability analysis. XRD pattern reveals that the CdXZn1-XS thin films are polycrystalline in nature with hexagonal crystal structure. FE-SEM micrograph displays that these CdXZn1-XS thin films exhibit the different sizes of sphere-like nanostructures by varying the X value. The optical absorption study indicates that drastic variation in band gap energy of CdXZn1-XS thin films. In advance photovoltaic measurements, CdXZn1-XS thin films are to be studied by forming the photoelectrochemical (PEC) cell having CdXZn1-XS/0.5 M (Na2SO3)/C configuration. The efficiency values of CdXZn1-XS are found to be 0.2, 0.35, 0.32, 0.25, and 0.23 % respectively at X content. |
Databáze: | OpenAIRE |
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