Mercury halide B(2Σ+) vibrational distributions from dissociative excitation reactions of Hg halides with Xe(3P2) and N2(A,3Σ+u)

Autor:	T. D. Dreiling, D. W. Setser
Rok vydání:	1983
Předmět:	Chemistry General Physics and Astronomy Halide chemistry.chemical_element Photochemistry Chemical reaction Spectral line Mercury (element) symbols.namesake Xenon Boltzmann constant symbols Physical chemistry Emission spectrum Physical and Theoretical Chemistry Excitation
Zdroj:	The Journal of Chemical Physics. 79:5439-5444
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.445707
Popis:	The HgX(B 2Σ+–X 2Σ+), X=Cl, Br, I, spectra from the dissociative excitation reactions of N2(A 3Σ+u, v=0, 1) and Xe(3P2) with several mercuric and methylmercury halides have been simulated to assign the HgX(B) vibrational distributions. The distributions from the methylmercury halides could be described as Boltzmann types with temperatures ranging from 1000 K for N2(A)+CH3HgI to 9000 K for Xe(3P2)+CH3HgCl. The distributions from the mercuric halides are non‐Boltzmann and the 〈fV〉 are somewhat higher than for the CH3HgX compounds. The initial HgX(B) vibrational distributions are used to discuss the state‐to‐state quenching mechanisms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2fd7af6ac4dc07a40ec4835f11ccec96 https://doi.org/10.1063/1.445707 Zobrazit plný text záznamu