4- vs. 5-phenylquinolinolate aluminum (III) isomers

Autor:	Simón E. López, Pavel Anzenbacher, Cesar Perez-Bolivar, Ligia Llovera
Rok vydání:	2010
Předmět:	Ligand Biophysics chemistry.chemical_element General Chemistry Electroluminescence Condensed Matter Physics Photochemistry Biochemistry Atomic and Molecular Physics and Optics chemistry Aluminium Michael reaction Physical stability Luminescence Spectroscopy
Zdroj:	Journal of Luminescence. 130:145-152
ISSN:	0022-2313
DOI:	10.1016/j.jlumin.2009.08.004
Popis:	A method for the synthesis of 4-arylquinolinolate ligand and their Al III complexes based on Michael reaction of 2-methoxyaniline with 1-phenylpropenones was developed. The resulting 4-aryl-8-methoxyquinoline was demethylated and converted to corresponding Al III complexes. Photophysical properties of two 4-aryl-Alq 3 derivatives were then compared with properties of the parent Alq 3 and a 5-phenyl-Alq 3 congener. It appears that the 5-aryl derivatives show improved luminescence but also decreased physical stability. Electroluminescence of the prepared materials is presented and compared to Alq 3 and a 5-phenyl-Alq 3 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2fb9e821809effecf6d227fd3a41f68c https://doi.org/10.1016/j.jlumin.2009.08.004 Zobrazit plný text záznamu Full Text from ScienceDirect