Highly Stereoselective Synthesis of 2-Methyl-1,3-dienes by Palladium-Catalyzed Cross-Coupling Reaction with Trimethylaluminum

Autor: Risa Takehana, Hajime Yokoyama, Takao Sanga, Yoshiro Hirai, Aoi Hosomori, Masahiro Miyazawa
Rok vydání: 2014
Předmět:
Zdroj: Synlett. 25:531-534
ISSN: 1437-2096
0936-5214
DOI: 10.1055/s-0033-1340477
Popis: Palladium-catalyzed cross-coupling reaction using tricyclohexylphosphine can be used to convert a range of 2-bromo-1,3-dienes efficiently and selectively to the corresponding methyl-branched conjugated dienes.
Databáze: OpenAIRE