Cleavage reactions of alkylcobaloximes with anhydrous hydrogen chloride

Autor:	Stuart B. Fergusson, Michael C. Baird
Rok vydání:	1982
Předmět:	chemistry.chemical_classification Chlorinated solvents Cleavage (embryo) Medicinal chemistry Homolysis Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Anhydrous Bibenzyl Organic chemistry Physical and Theoretical Chemistry Hydrogen chloride Alkyl Isopropyl
Zdroj:	Inorganica Chimica Acta. 63:41-45
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(00)81889-7
Popis:	The compounds RCo(DH) 2 py (R = alkyl; DH = dimethylglyoximato anion) are cleaved by anhydrous HCl in chlorinated solvents to give RH (R = Me, Et, isopropyl, neopentyl, cyclohexyl), probably via an S E 2 process. When R = benzyl, homolysis of the cobalt-carbon bond becomes the predominant reaction, yielding bibenzyl.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f7a9197c1aa21f500dc0eb49785a210 https://doi.org/10.1016/s0020-1693(00)81889-7 Zobrazit plný text záznamu