Exploring Te-Te Bond Cleavage with Palladium(II): Synthesis, X-ray Structural Characterization, and Optical Features of Tellurolate and Telluro-Ether Complexes of Palladium(II)

Autor:	Bárbara Tirloni, Camila Nunes Cechin, Ernesto Schulz Lang, Marcelo Barbalho Pereira, Gelson Manzoni de Oliveira, Giovanny Ferro Razera
Rok vydání:	2016
Předmět:	010405 organic chemistry Band gap X-ray chemistry.chemical_element Infrared spectroscopy Ether 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Elemental analysis Spectroscopy Bond cleavage Palladium
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 642:239-245
ISSN:	0044-2313
DOI:	10.1002/zaac.201500779
Popis:	The focus of this study was to explore reactions of (RTe)2 with palladium(II) salts. These reactions led to Te–Te bond cleavage and the formation of three tellurolate-bridged dinuclear complexes and a mononuclear telluro-ether palladium(II) complex. The methodologies used yielded single source precursors for interesting materials. UV/vis spectroscopy results supported the measured optical bandgap for the complexes in the solid state. A study on the structure of all complexes in the solid state was carried out using single-crystal X-ray diffraction. Other analytical methodologies, such as elemental analysis and infrared spectroscopy, were also used for the characterization of the complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f74bba80e5a102a4fc939de0d666750 https://doi.org/10.1002/zaac.201500779 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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