Reactions of ferrocene and acetylferrocene with carbon-centered free radicals

Autor:	Enrico Baciocchi, E. Muraglia, Barbara Floris
Rok vydání:	1993
Předmět:	Reaction mechanism chemistry.chemical_compound chemistry Ferrocene Nucleophile Radical Organic Chemistry Electrophile Acetylferrocene Medicinal chemistry Metallocene Homolysis
Zdroj:	The Journal of Organic Chemistry. 58:2013-2016
ISSN:	1520-6904 0022-3263
Popis:	Homolytic substitutions of ferrocene with a variety of carbon-centered radicals have been investigated. Reactions with synthetic utility have only been obtained in the cases of ambiphilic radicals (cyanomethyl and alkoxycarbonylmethyl), whereas nucleophilic radicals (R . and RCO . ) give relatively low yields, and no reaction at all is observed with electrophilic radicals (malonyl, methylmalonyl). The reaction of acetylferrocene with cyanomethyl and ethoxycarbonylmethyl radicals leads to the formation of homo- and heteroannular disubstituted products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f7233338f474ce9e29ffb5adb83817c https://doi.org/10.1021/jo00060a011 Zobrazit plný text záznamu