Ion Transport Study in Corn Starch-NaHSO3 Based Polymer Electrolytes

Autor:	Khadijah Hilmun Kamarudin, Kok Sheng Chan, Fatin Farhana Awang, Mohd Faiz Hassan
Rok vydání:	2021
Předmět:	Chemical engineering Chemistry Polymer electrolytes Corn starch Ion transporter
Zdroj:	Scientific Research Journal. 18:17-36
ISSN:	2289-649X 1675-7009
DOI:	10.24191/srj.v18i2.11985
Popis:	In this work, different amounts of sodium bisulfite, NaHSO3 (5wt.% to 40wt.%), were dissolved in a corn starch polymer host to synthesize solid polymer electrolyte (SPE) using a solution casting technique. Then, the films prepared were characterised using non-destructive electrical impedance spectroscopy to determine SPE films' conductivity and electrical transport properties. The highest conductivity of the sample at ambient temperature was recorded at 15wt. % of NaHSO3 with a value of 2.22 × 10-4 Scm-1. Moreover, the ion transport parameters at room temperature are found to be 2.41 × 10-7 cm2s-1, 9.39 × 10-6 cm2V-1s-1, 1.70 × 1019 cm-3 for D, µ and n, respectively. The conductivity of the samples was found dependent on diffusion coefficient, D and mobility, µ of ions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f441234980c9bedf3d0adf6de025182 https://doi.org/10.24191/srj.v18i2.11985 Zobrazit plný text záznamu