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7 Li NMR relaxation has been used to study lithium-ion diffusion in layer-structured SnS 2 . Keeping the Li intercalation degree in Li x SnS 2 below x = 0.49, the Li ions preferentially occupy sites in the van der Waals gap between the SnS 2 sheets. In contrast to conventional NMR spin-lattice relaxation (SLR) rate measurements in the laboratory frame of reference, which are sensitive to rather fast Li exchange processes, with the help of spin-locking SLR NMR slower Li motions were extracted from characteristic diffusion-induced rate peaks. The latter contain information on both Li + activation energies E a and Li ion jump rates τ − 1 characterizing the elementary steps of Li + hopping. Our results point to two different diffusion processes ( E a (I) = 0.38 eV; E a (II) = 0.28 eV), a slower and a faster one, observable directly after chemical Li insertion. Interestingly, the diffusion behaviour irreversibly changes when the sample has been exposed to temperatures as high as 573 K. Diffusion-induced NMR rates and corresponding line shapes are discussed with respect to an inhomogenous distribution of Li ions in SnS 2 , which seems to be present directly after Li intercalation. |
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