The influence of conformational defects on the development of structural phase transition in tetracosane C24H50
Autor: | S A Gureva, V A Marikhin, L P Myasnikova, B Z Volchek, D A Medvedeva |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Journal of Physics: Conference Series. 2103:012091 |
ISSN: | 1742-6596 1742-6588 |
DOI: | 10.1088/1742-6596/2103/1/012091 |
Popis: | The kinetics of the first-order solid-state structural transition in monodisperse n-alkanes samples of even tetracosane C24H50 was studied by FTIR spectroscopy. The existence of many irregular conformers in solid phases of tetracosane, the concentration of which reaches a maximum when approaching the melting temperature, has been demonstrated. The existence of these defective molecules promotes transitions between different rotator phases in the solid state. |
Databáze: | OpenAIRE |
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