Mild and highly efficient method for the oxidation of sulfides and oxidative coupling of thiols catalyzed by Fe3O4@MCM-41@VO-SPATB as efficient and magnetically recoverable nanocatalyst

Autor:	Arash Ghorbani-Choghamarani, Mohsen Nikoorazm, Farshid Ghorbani, Zahra Erfani
Rok vydání:	2018
Předmět:	010405 organic chemistry Nanoporous Ligand Vanadium chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Redox Combinatorial chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry MCM-41 Oxidative coupling of methane Magnetite
Zdroj:	Journal of the Iranian Chemical Society. 16:553-562
ISSN:	1735-2428 1735-207X
Popis:	The use of oxo vanadium complex with s-propyl-2-aminobenzothioate ligand immobilized onto functionalized magnetic nanoporous MCM-41(Fe3O4@MCM-41@VO-SPATB) as efficient and magnetically recoverable nanocatalyst for oxidation of sulfides into sulfoxides and oxidative coupling of thiols into disulfides using H2O2 as green oxidant is presented. This method provides much improved modification of oxidation reactions in terms of mild reaction conditions, short reaction time and good-to-excellent yields of products. Another important feature of this method is the ability to reuse the magnetite nanocatalyst for several times with no loss of its catalytic activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f239d6028b48b85aae09d11594ca823 https://doi.org/10.1007/s13738-018-1536-3 Zobrazit plný text záznamu Full text from SpringerLink