Dual chiral recognition system involving cyclodextrin derivatives in capillary electrophoresis

Autor:	Michael Schleimer, Sabine Mayer, Volker Schurig
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Chromatography Cyclodextrin Chemistry Capillary action Elution Mechanical Engineering technology industry and agriculture Filtration and Separation Cyclodextrin Derivatives Capillary electrophoresis Phase (matter) polycyclic compounds Recognition system Enantiomer
Zdroj:	Journal of Microcolumn Separations. 6:43-48
ISSN:	1520-667X 1040-7685
DOI:	10.1002/mcs.1220060109
Popis:	An immobilized chiral stationary phase, Chirasil-Dex, coated onto the inner surface of a 50 μm i.d. capillary and cyclodextrin derivatives added to the running buffer were simultaneously used for the study of enantiomer separations by capillary electrophoresis. Dependent on the cyclodextrin concentration in the mobile phase, a reversal of the elution order of enantiomers due to dual chiral recognition mechanisms was observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f2139d72f5830fff08a4bcbb3942058 https://doi.org/10.1002/mcs.1220060109 Zobrazit plný text záznamu Plný text