Annealing effect on the optical and solid state properties of cupric oxide thin films deposited using the Aqueous Chemical Growth (ACG) method

Autor:	Sylvester Lekoo Mammah, Fidelix Ekeoma Opara, VB Omubo-Pepple, Sabastine Ezugwu, Fabian I. Ezema, J. E. Ntibi
Rok vydání:	2013
Předmět:	Materials science Annealing (metallurgy) Analytical chemistry Oxide Mineralogy Absorbance Condensed Matter::Materials Science chemistry.chemical_compound Crystallinity chemistry Transmittance Direct and indirect band gaps Thin film Refractive index
Zdroj:	Natural Science. :389-399
ISSN:	2150-4105 2150-4091
DOI:	10.4236/ns.2013.53052
Popis:	Thin films of CuO having an average thickness of 720 nm were deposited on clean glass substrates using the Aqueous Chemical Growth (ACG) method with Cu(NO3)2 and C6H12N4 as precursors and annealed at different temperatures in order to determine the effect of annealing temperature on their optical and solid state properties. The study was carried out using Rutherford Backscattering (RBS) spectroscopy for t thickness and chemical composition, X-Ray Diffraction (XRD) for crystallographic structure and a UV-VIS spectrophotometer for spectral analysis. The results indicate that the absorbance and absorption/extinction coefficient of the films vary inversely with annealing temperature while the transmittance, reflectance, direct band gap, real/imaginary dielectric constants and refractive index vary directly with annealing temperature. The results further indicate an improvement in crystallinity as annealing temperature increases. The as-deposited and annealed ACG CuO thin films were found to be suitable for use as window layer in solar cells among other electronic and optoelectronic applications.
Databáze:	OpenAIRE
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