An investigation of rotational diffusion of poly(γ-benzyl-L-glutamate) in dilute solution by 13C nuclear magnetic relaxation

Autor:	P.A. Harris, T.J. Holton, Colin Price, Frank Heatley
Rok vydání:	1977
Předmět:	Nuclear magnetic relaxation Deuterated DMF Diffusion General Physics and Astronomy Rotational diffusion Rotation chemistry.chemical_compound Nuclear magnetic resonance chemistry L glutamate Helix Relaxation (physics) Physical chemistry Physical and Theoretical Chemistry
Zdroj:	Chemical Physics Letters. 49:504-507
ISSN:	0009-2614
DOI:	10.1016/0009-2614(77)87025-5
Popis:	13 C spinlattice relaxation times, T 1 , for the α-carbon nuclei of poly(γ-benzyl-L-glutamate) fractions in deuterated DMF are shown to be governed by the diffusion coefficient for rotation about the helix axis, leading to an approximately linear dependence of T 1 on molecular weight. The α- 13 C spinspin relaxation times, T 2 , which decrease with increase in molecular weight, are found to be influenced by both the axial and end-over-end rotational diffusion coefficients.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f0ebbec69b6f6c6a744a50f4ce0be9d https://doi.org/10.1016/0009-2614(77)87025-5 Zobrazit plný text záznamu