ChemInform Abstract: Oxidative Electrochemistry of the Cluster (Co4(CO)9(HC(PPh2)3)). Reactivity with the Nucleophiles PPh3 and P(OMe)3

Autor:	Rodolphe Jund, Maurice Gross, J. Rimmelin, Ali A. Bahsoun
Rok vydání:	2010
Předmět:	Reaction mechanism Electron transfer Nucleophile Chemistry Intramolecular force Cluster (physics) Reactivity (chemistry) General Medicine Oxidative phosphorylation Electrochemistry Medicinal chemistry
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199106048
Popis:	The one-electron-oxidized cluster [Co4(CO)9{HC(PPh2)3}]˙+ reacts with PPh3 and P(OMe)3. The reaction mechanisms involve the substitution of CO by PR3. The P(OMe)3 substituted cluster is stable, whereas the PPh3 substituted cluster undergoes an intramolecular electron transfer which regenerates the initial cluster. A general reaction scheme is proposed for the one-electron-oxidized and the one-electron-reduced cluster.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f04b9338d49e0cf8e09889a23a94f6e https://doi.org/10.1002/chin.199106048 Zobrazit plný text záznamu Plný text