Paramagnetic ([5]Trovacenyl)phenylphosphane: Intramolecular Electronic Communication and Construction of Heterobimetallic Palladium and Chromium Complexes

Autor:	Christoph Elschenbroich, Clemens Pietzonka, Feng Lu, Olaf Burghaus, Klaus Harms
Rok vydání:	2015
Předmět:	Chemistry Inorganic chemistry chemistry.chemical_element Magnetic susceptibility law.invention Inorganic Chemistry Paramagnetism Crystallography Chromium Transition metal law Intramolecular force Electron paramagnetic resonance Spectroscopy Palladium
Zdroj:	European Journal of Inorganic Chemistry. 2015:2883-2888
ISSN:	1099-0682 1434-1948
Popis:	Group 15 P-atom-bridged paramagnetic unsymmetric sandwich binuclear di([5]trovacenyl)phenylphosphane (2··) was prepared and characterized by mass spectroscopy, elemental analysis, and X-ray diffraction analysis (XRD). The investigation of 2·· by means of cyclic voltammetry (CV), electron paramagnetic resonance (EPR) spectroscopy, and magnetic susceptibility (SQUID) revealed weak intramolecular electronic communication. The coordination ability of 2·· with the transition metals palladium and chromium was explored to afford unprecedented heterobimetallic complexes 34· and 44·, respectively, which were characterized by mass spectroscopy, elemental analysis, and/or X-ray diffraction analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2f02951970b110143870375d1b4089d0 https://doi.org/10.1002/ejic.201500095 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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