Regioselective electrophilic alkylation of anilines with phenylacetylene in the presence of montmorillonite KSF

Autor:	Pietro Moggi, Giovanni Sartori, Elena Marzi, Franca Bigi, A. Arienti, Fabio Tarantola, Raimondo Maggi, Massimo Rastelli
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Phenylacetylene Chemistry Organic Chemistry Drug Discovery Electrophile Regioselectivity Alkylation Biochemistry Montmorillonite KSF Medicinal chemistry
Zdroj:	Tetrahedron. 53:3795-3804
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(97)00100-2
Popis:	Substituted anilines react with phenylacetylene in the presence of montmorillonite KSF affording 1,1-diarylethylenes 3 in good yields and excellent selectivities. In the presence of an excess of phenylacetylene, para-toluidine and para-anisidine give the corresponding 2,6-bis(1-phenylvinyl)anilines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2ee011ff598c6dad9894404af78e1a49 https://doi.org/10.1016/s0040-4020(97)00100-2 Zobrazit plný text záznamu Full Text from ScienceDirect