Polystyrene-supported bromoderivative of 2-pyrrolidone: synthesis, characterization and application in microwave-assisted bromination reactions
| Autor: | Ebey P. Koshy, Beena Mathew, Anjaly Mathew |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Halogenation 02 engineering and technology General Chemistry Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Combinatorial chemistry 0104 chemical sciences Matrix (chemical analysis) chemistry.chemical_compound chemistry Reagent Yield (chemistry) Materials Chemistry Polystyrene 2-Pyrrolidone 0210 nano-technology Microwave |
| Zdroj: | Polymer Bulletin. 79:905-920 |
| ISSN: | 1436-2449 0170-0839 |
| Popis: | A novel, microwave safe and recyclable polymeric reagent was prepared by anchoring bromoderivative of 2-pyrrolidone in the polymer matrix of 3% tetraethyleneglycol diacrylate cross-linked polystyrene. The synthetic utility of the prepared polymeric reagent was demonstrated by the efficient bromination of unsaturated compounds, activated aromatic compounds and also for the α-bromination of ketones under microwave activation. Operational simplicity, moderate to excellent yield of the products, shorter reaction time and dry reaction medium are the foremost attraction of this protocol. Moreover, the synthesized functional polymer was stable under standard laboratory conditions and can be kept for several months without any significant loss of activity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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