ChemInform Abstract: Palladium-Catalyzed Carbonyl Allylation of Aldehydes by Allylic Cyclic Carbonates

Autor: Suk-Ku Kang, Chan Hee Park, S.‐B. Jang, Dong-Chul Park
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 26
ISSN: 0931-7597
Popis: Palladium(O)-catalyzed allylation of aldehydes by allylic cyclic carbonates with SnCl2 proceeded smoothly to afford 1,3-diols with high diastereocontrol. For the exomethylene cyclic carbonate, allylation with aldehydes furnished 1,4-diols or 1,5-diols depending on amount of aldehydes.
Databáze: OpenAIRE