Popis: |
Plasma oxidation of Ti, Cu and Ni was carried out using a conventional diode-type glow discharge system. Structural and photoelectrochemical properties of the oxide layers formed were examined. Electron diffraction confirmed the formation of a TiO2, Cu2O/CuO, and NiO layer on the Ti, Cu, and Ni surfaces, respectively, after the plasma oxidation. Photoelectrochemical solar cells were fabricated using the oxide layers formed as a semiconductor electrode. The TiO2 electrodes showed moderate photoresponse under anodic potentials in a methanol aqueous solution, while the Cu2O/CuO and NiO electrodes showed a weak photoresponse under cathodic potentials. In conclusion, the TiO2 layers prepared by plasma oxidation work well as a semiconductor electrode for a photoelectrochemical cell and are stable in methanol solution. |