Biotreatment Of Produced Water Containing Hydrate Inhibitors

Autor: Arnold Janson, Ana Santos, Simon Judd, Samer Adham, Altaf Hussain, Samir Gharfeh
Rok vydání: 2014
Předmět:
Zdroj: Qatar Foundation Annual Research Conference Proceedings Volume 2014 Issue 1.
Popis: With proper treatment to remove organics and inorganics, the produced water (PW) generated during oil and gas extraction can be reused as process water. Biotreatment is generally regarded as the most cost-effective method for organics removal and although widely used in industrial wastewater treatment, PW biotreatment installations are limited. The research described in this paper focused on the aerobic biotreatment of PW from the Qatari "North Shore" gas field supplemented with either 1.5% kinetic hydrate inhibitor (KHI) or 1.5% thermodynamic hydrate inhibitor (monoethylene glycol, MEG). KHI and MEG are "field chemicals" added off-shore during the winter months. This research was part of a larger project assessing the biotreatability of produced water from both summer and winter seasons. Although the feed pH was 4.5 and the biomass used as seed was cultured at pH 5.5, the bioreactor pH stabilized at 2.6 when KHI or MEG were added. Active biological oxidation was demonstrated in our tests for a period of 7 months through COD tests and in-situ dissolved oxygen (DO) and oxygen uptake rate (OUR) measurements. When 1.5% KHI in PW was added to the bioreactor, the DO decreased sharply and the OUR increased quickly from 0.2 to 1.9 mg O2/L.min. The COD results indicated that 43% and 81% of the organics present were removed through biotreatment of PW dosed with 1.5% KHI or MEG respectively. The concentration of 2-butoxyethanol (one of the two main components in KHI) was reduced from >5,000 mg/l to
Databáze: OpenAIRE