Bistable Polymorphs Showing Diamagnetic and Paramagnetic States of an Organic Crystalline Biradical Biphenyl-3,5-diyl Bis(tert-butylnitroxide)

Autor:	and Takashi Nogami, Shinichiro Mashiyama, Masanori Yasui, Takayuki Ishida, Hirokazu Nishimaki
Rok vydání:	2006
Předmět:	Biphenyl Phase transition Bistability Chemistry Stereochemistry General Chemical Engineering General Chemistry Paramagnetism Crystallography chemistry.chemical_compound Phase (matter) Materials Chemistry Diamagnetism Tert-butylnitroxide
Zdroj:	Chemistry of Materials. 18:3602-3604
ISSN:	1520-5002 0897-4756
DOI:	10.1021/cm061222k
Popis:	The practically diamagnetic phase of the title biradical underwent a solid-state phase transition at 350 K with a drastic χmolT jump by an almost ideal value of 1 cm3 K mol-1 to give a stable S = 1 paramagnetic state.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2e53b99839fe1818328f861d19f6df0d https://doi.org/10.1021/cm061222k Zobrazit plný text záznamu