Highly Activated Second-Generation Grubbs–Hoveyda Catalyst Driven by Intramolecular Steric Strain

Autor:	Hiroki Miyazaki, Rina Igarashi, Shuichi Nakamura, Reo Makino, Sae Inukai, Chika Takagi, Kento Shimowaki, Yuya Sugiyama, Masato Matsugi, Yuki Kobayashi
Rok vydání:	2016
Předmět:	010405 organic chemistry Chemistry Ligand Intramolecular force Organic Chemistry Salt metathesis reaction Moiety 010402 general chemistry Photochemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis
Zdroj:	Synlett. 27:2352-2356
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0035-1562468
Popis:	Various Grubbs–Hoveyda second-generation catalysts activated by intramolecular steric strain were prepared. The variant bearing a 9-anthracenyl group in the ligand moiety exhibited the highest catalytic activity. The new anthracenyl-type-activated catalyst was used in a ring-closing metathesis reaction to effectively provide a 4-substituted product effectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2e448208d4c71678d979e8819bc596b7 https://doi.org/10.1055/s-0035-1562468 Zobrazit plný text záznamu