Atrazine interactions with clay minerals: Kinetics and equilibria of sorption
Autor: | Hideomi. Kodama, Glen F. R. Gilchrist, Donald S. Gamble, Shahamat U. Khan |
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Rok vydání: | 1993 |
Předmět: | |
Zdroj: | Journal of Agricultural and Food Chemistry. 41:1748-1755 |
ISSN: | 1520-5118 0021-8561 |
DOI: | 10.1021/jf00034a043 |
Popis: | A novel technique using on-line microfiltration and HPLC analysis has been rued to study sorption kinetics and sorption equilibrium of the herbicide atrazine with the clay minerals montmorillonite, kaolinite, and illite and the clay fraction of a soil. Fast and slow labile sorption have been observed for atrazine along with a reversible but kinetically slow sorption/desorption process that is consistent with diffusion of pesticide into the interior of the clay particles. Labile sorption capacity, mole fraction site coverage, labile sorption equilibrium function, and distribution coefficient were determined for the clay minerals un aqueous slurries with atrazine |
Databáze: | OpenAIRE |
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