Synthesis and Characterization of Complexes of Thallium(III) Halides with Substituted Imidazoles

Autor:	M. R. Bermejo, B. Fernández, M. E. Gómez, M. I. Fernández
Rok vydání:	1992
Předmět:	Inorganic chemistry chemistry.chemical_element Halide Medicinal chemistry Characterization (materials science) Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Elemental analysis Proton NMR Thallium Physical and Theoretical Chemistry Acetonitrile Spectroscopy
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 22:759-773
ISSN:	1532-2440 0094-5714
DOI:	10.1080/15533179208020243
Popis:	The reactions between T1X (X = Cl, Br, or I) and substituted imidazoles [(2-methyl-imidazole (2-Me-Im), 2-phenyl-imidazole (2-Phen-Im), 2-ethyl-imidazole (2-Et-Im), 1,2-dimethyl-imidazole (1,2-Me2-Im) and l-methyl-2-phenyl-imidazole (1-Me,2-Phen-Im)] in various donor-acceptor molar ratios have been studied. The complexes formed have been characterized by elemental analysis. The complexes are monomeric solids and non-electrolytes in acetonitrile. Possible structures are discussed on the basis of H NMR and i.r. spectroscopy and comparison with structures in the literature.
Databáze:	OpenAIRE
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