Carbon Oxide Hydrogenation over GdBO3 (B = Fe, Mn, Co) Complex Oxides: Effect of Carbon Dioxide on Product Composition
| Autor: | T. F. Sheshko, I. V. Chislova, L. V. Yafarova, O. K. Powell, Yu. M. Serov, A. V. Koroleva, A. A. Sharaeva, Irina A. Zvereva |
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| Rok vydání: | 2020 |
| Předmět: |
Hydrogen
010405 organic chemistry General Chemical Engineering Inorganic chemistry Oxide Energy Engineering and Power Technology chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Ion chemistry.chemical_compound Fuel Technology Adsorption chemistry Geochemistry and Petrology Carbon dioxide Carbon Carbon monoxide |
| Zdroj: | Petroleum Chemistry. 60:571-576 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544120050114 |
| Popis: | The catalytic properties of GdFeO3, GdСоO3, and GdMnO3 perovskite-type complex oxides in carbon oxide hydrogenation are studied. A correlation between the composition and catalytic properties of the oxide is found. It is shown that carbon monoxide conversion increases in the following order: GdFeO3 < GdMnO3 ≤ GdСоO3; carbon dioxide conversion increases in the reverse order. Differences in the catalytic characteristics of GdFeO3, GdMnO3, and GdCoO3 are attributed to different forms of chemisorbed CO, CO2, and H2 and the hydrogen mobility across the catalyst surface. The introduction of carbon dioxide into the reaction mixture suppresses the formation of olefins and causes an increase in methane yield. In the catalytic process, GdCoO3 is partially decomposed into Gd2O3, Co, and Gd2O2CO3. It is assumed that carbon oxides are adsorbed by Gd3+ ions (A site), while transition metal ions (B site) are responsible for the formation of atomic hydrogen. It is presumed that carbon sites formed on the surface differ in catalytic activity: some of them are responsible for the formation of unsaturated hydrocarbons, and the others are responsible for the formation of paraffins. |
| Databáze: | OpenAIRE |
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