(Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry

Autor:	J. Scott McIndoe, Ward T. Robinson, D. A. Clemente, Brian K. Nicholson
Rok vydání:	2008
Předmět:	Crystallography Chemistry chemistry.chemical_element Molecule Manganese Crystal structure Physical and Theoretical Chemistry Symmetry (geometry) Condensed Matter Physics
Zdroj:	Structural Chemistry. 19:489-492
ISSN:	1572-9001 1040-0400
Popis:	There are two molecules in the asymmetric unit of the P21/c unit cell of ClCH2Mn(CO)5, the first halomethyl complex of manganese to be structurally determined. The molecules are crystallographically independent, despite an apparent local centre of symmetry. The average bond parameters include Mn–Calkyl 2.128(8) A, C–Cl 1.811(8) A and Mn–C–Cl 116.4(4)°.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2e2452b4435c9d3708ff4c804216b497 https://doi.org/10.1007/s11224-008-9308-9 Zobrazit plný text záznamu Full text from SpringerLink