Cuvette-Based Electrogenerated Chemiluminescence Detection System for the Assessment of Polymerizable Ruthenium Luminophores
| Autor: | William L Odette, Hanadi F. Sleiman, Janine Mauzeroll, Andrew S. Danis, Sylvain Canesi, Samuel C. Perry |
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| Rok vydání: | 2017 |
| Předmět: |
Chemistry
Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry Photochemistry 01 natural sciences Catalysis Potentiostat 0104 chemical sciences Ruthenium law.invention Preliminary analysis Cuvette Bipyridine chemistry.chemical_compound law 0210 nano-technology Chemiluminescence |
| Zdroj: | ChemElectroChem. 4:1736-1743 |
| ISSN: | 2196-0216 |
| DOI: | 10.1002/celc.201600879 |
| Popis: | Herein, we validate a novel cuvette-based approach to measuring electrogenerated chemiluminescence (ECL) employing the hyphenation of a commercial spectrometer and potentiostat. The new experimental design provides simultaneous acquisition of electrochemical and ECL data allowing complementary analysis by both techniques. Preliminary analysis of an organometallic ECL standard, tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)32+), and tripropylamine (TPA), showed excellent reproducibility both in terms of the electrochemistry and the ECL signal. Equally as important, the acquired electrochemistry and ECL from the Ru(bpy)32+ / TPA system served as a baseline for evaluating the ECL response of polymerizable ruthenium luminophores. |
| Databáze: | OpenAIRE |
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