Reaction of 1,1,3 -TRI-(?-chloroethoxy)propane with some sodium alcoholates

Autor:	M. F. Shostakovskii, F. P. Sidel'kovskaya, T. T. Minakova
Rok vydání:	1964
Předmět:	Sodium Acetal Acrolein chemistry.chemical_element Alcohol General Chemistry Medicinal chemistry chemistry.chemical_compound chemistry Propane Chlorine Molecule Organic chemistry Excess sodium
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13:2009-2011
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00844510
Popis:	1. in the reaction of 1,1,3-tri-(β-chloroethoxy)propane with two moles of sodium methylate, two atoms of chlorine are replaced by methoxy groups, forming 1,1-di-(β-methoxyethoxy)-3-(β-chloroethoxy)propane. 2. The reaction of 1,1,3-tri-(β-chloroethoxy)propane with alcoholates of n-butyl and tert-butyl alcohols leads to splitting out of two molecules of HCl and the production of 1,1-divinyloxy-3-(β-chloroethoxy)propane. Under the action of excess sodium methylate on 1,1,3-tri-(β-chloroethoxy)propane, two products are formed: 1,1,3-tri-(methoxyethoxy) propane and the 1,1-dimethoxyethyl acetal of acrolein.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2e0a289acee26702ea6ae8e6844e6739 https://doi.org/10.1007/bf00844510 Zobrazit plný text záznamu Full text from SpringerLink