Modular tripodal receptors for the hydrosulfide (HS−) anion
Autor: | Nathanael Lau, Michael D. Pluth, Lev N. Zakharov |
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Rok vydání: | 2018 |
Předmět: |
010405 organic chemistry
Stereochemistry Hydrogen sulfide Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Synthetic Receptors Materials Chemistry Ceramics and Composites Receptor |
Zdroj: | Chemical Communications. 54:2337-2340 |
ISSN: | 1364-548X 1359-7345 |
DOI: | 10.1039/c7cc09405a |
Popis: | Hydrogen sulfide (H2S) is an endogenously-produced gasotransmitter and is predominantly speciated as HS- at physiological pH. Despite this importance, reversible binding of HS- to synthetic receptors remains rare and confined to highly-engineered receptor systems. Here we demonstrate the generality of reversible HS- binding in a family of tren-based receptors. |
Databáze: | OpenAIRE |
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