A new stereo- and regioselective synthesis of (±)-sesamin involving a β-scission of alkoxyl radicals as the key step1

Autor:	Kazuhiko Orito, Hiroshi Suginome, Kaoru Yorita
Rok vydání:	1991
Předmět:	Bicyclic molecule Stereochemistry Organic Chemistry Regioselectivity Cyclopentanone Ring (chemistry) Biochemistry chemistry.chemical_compound chemistry Sesamin Drug Discovery Stereoselectivity Tetrahydrofuran Bond cleavage
Zdroj:	Tetrahedron Letters. 32:5999-6002
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)79448-2
Popis:	A new stereo- and regioselective synthesis of (±)-sesamin (a representative lignan) based on our general method for the transformation of a cyclopentanone ring into a tetrahydrofuran ring involving a regioselective β-scission of the alkoxyl radicals is reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2dff2aaa2f6bb64ef1527ed21d0e9415 https://doi.org/10.1016/s0040-4039(00)79448-2 Zobrazit plný text záznamu