Synthesis of furan from allenic sulfide derivatives

Autor:	Jianbo Wang, Xiu Zhang, Lingling Peng, Zhe Zhang, Zhenzhen Zhong, Yan Zhang, Jie Ma
Rok vydání:	2009
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Nucleophile Sulfide Furan Reagent Allene Substituent Organic chemistry General Chemistry
Zdroj:	Science in China Series B: Chemistry. 52:1622-1630
ISSN:	1862-2771 1006-9291
DOI:	10.1007/s11426-009-0224-7
Popis:	In this paper, we report the synthesis of furan derivatives from allenic sulfides. By the reaction with NaH, β-Hydroxyl allenic sulfides were found to generate furan products in excellent yields with the removal of phenylthio group. β-Aldehyde allenic sulfides were found to give similar furan products with one more substituent when treated with additional nucleophilic reagents. β-ketone allenic sulfides can also cyclize to give furan derivatives with the promotion of P2O5.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2dfa828dad0c182a74f6b1fcdb361ad0 https://doi.org/10.1007/s11426-009-0224-7 Zobrazit plný text záznamu Full text from SpringerLink