Reductions of CO and CN groups with the systems composed of (η5-C5H5)2MoH2 and acids

Autor:	Yutaka Fujiwara, Susumu Kurishima, Naoya Matsumoto, Norihiro Sekizuka, Takashi Ito, Makoto Natori, Miho Koga, Ken-ichiro Yoshioka, Makoto Minato
Rok vydání:	1998
Předmět:	Inorganic Chemistry Chemistry Organic Chemistry Materials Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 569:139-145
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(98)00782-7
Popis:	Selective reductions of organic compounds, such as carbonyl compounds and imines, using a system composed of Cp 2 MoH 2 and acids are examined. This system can reduce the substrates under mild conditions. Extremely high diastereoselectivity was achieved in the reduction of 4- t -butylcyclohexanone. The reactivity of imines depends on their structure. Aromatic imines are found to be more reactive than aliphatic imines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2de2dc3d0b204c2ae0c9e70a5a18ea59 https://doi.org/10.1016/s0022-328x(98)00782-7 Zobrazit plný text záznamu Full Text from ScienceDirect