An abnormal phenomenon on O2(a1Δ) deactivation by deuterated alcohols

Autor:	Jing Leng, Yang Heping, Cunhao Zhang, Guohe Sha, Junhui Wang
Rok vydání:	2013
Předmět:	Chemistry Hydrogen bond Intermolecular force General Physics and Astronomy Liquid phase Solvent Reaction rate constant Deuterium Molecule Physical chemistry Organic chemistry Physics::Chemical Physics Physical and Theoretical Chemistry Spectroscopy
Zdroj:	Chemical Physics Letters. 583:14-17
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2013.07.064
Popis:	The deactivation rate constants (kΔ) of O2(a1Δ) by several gaseous alcohols were measured using a quasi-static method. The results indicate that the gaseous kΔ values for normal alcohols are smaller than their corresponding liquid-phase data, well consistent with Schmidt’s model. However, for deuterated alcohols, an abnormal phenomenon that their gaseous kΔ values are evidently larger than their corresponding liquid-phase data was first observed. It is likely related to the O–D bonds in their molecules which can form more stable liquid-phase clusters via intermolecular hydrogen bonds and exhibit different vibrational constants in gas and liquid phase.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2dd087327d5e755f5faaaf545d1bb481 https://doi.org/10.1016/j.cplett.2013.07.064 Zobrazit plný text záznamu Full Text from ScienceDirect