Properties of semi-coke from co-pyrolysis of lignite and direct liquefaction residue of Shendong coal

Autor: Jiang-shan Ma, Yan-li Xue, Xiao-hong Li, Wen-ying Li
Rok vydání: 2015
Předmět:
Zdroj: Journal of Fuel Chemistry and Technology. 43:1281-1286
ISSN: 1872-5813
DOI: 10.1016/s1872-5813(15)30039-6
Popis: In order to make use of coal direct liquefaction residue efficiently, co-pyrolysis of Hulunbuir lignite and direct liquefaction residue (DLR) of Shendong coal were conducted in a fixed bed reactor under atmospheric pressure. The physicochemical properties of co-pyrolysis semi-coke were analyzed by scanning electron microscope, nitrogen adsorption-desorption, X-ray diffraction, Raman spectroscopy and thermogravimetric analyzer. The results show that DLR semi-coke and lignite semi-coke are cohered each other, because the DLR is softened and melted during co-pyrolysis. The specific surface area and pore volume of co-pyrolysis semi-coke decrease. Characterization of both XRD and Raman spectroscopy indicate that the order degree of co-pyrolysis semi-coke increases with the addition of DLR. Compared with the lignite semi-coke, the CO 2 gasification reactivity of co-pyrolysis semi-coke decreases.
Databáze: OpenAIRE