Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery
| Autor: | Xue-Tian Li, Chao-Qun Chen, Yu-Bin Dong, Gong-Jun Chen, Hui-Chao Ma |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Chemistry Metals and Alloys Homogeneous catalysis General Chemistry 010402 general chemistry 01 natural sciences Catalysis Coupling reaction 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal visual_art Polymer chemistry Materials Chemistry Ceramics and Composites visual_art.visual_art_medium |
| Zdroj: | Chemical Communications. 54:11550-11553 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc07208f |
| Popis: | The reported Cu(II) metal–organic cage (Cu3L2, 1) can be a highly active reusable catalyst to homogeneously catalyze the A3-coupling reaction in CHCl3 and can be heterogeneously recovered by simply adding 1,4-dioxane via formation of the insoluble metal–organic framework (Cu3L2(1,4-dioxane)1.5, 2). |
| Databáze: | OpenAIRE |
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