Boronate esters: Synthesis, characterization and molecular base receptor analysis
| Autor: | Gelen Gómez-Jaimes, Victor Barba |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Base (chemistry) Organic Chemistry Nuclear magnetic resonance spectroscopy Medicinal chemistry Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Molecular recognition chemistry Pyridine Organic chemistry Titration Lewis acids and bases Fluoride Triethylamine Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1075:594-598 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2014.06.078 |
| Popis: | The synthesis of three boronate esters obtained by reacting 4-fluorophenylboronic ( 1 ), 4-iodophenylboronic ( 2 ) and 3,4-chlorophenylboronic ( 3 ) acids with 2,4,5-trihidroxybenzaldehyde is reported. The structural characterization was determined by spectroscopic and spectrometric techniques. The boron atom was evaluated to acts as Lewis acid center in the reaction with pyridine (Py), triethylamine (TEA) and fluoride anion (F − ). The titration method was followed by UV–Vis and 11 B NMR spectroscopy; results indicate the good interaction with the fluoride ion but poor coordination towards pyridine in solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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