Syntheses and molecular self-assembly of chiral phosphoramidates

Autor:	Da-Ming Du, Xiang-Lin Jin, Wen-Ting Hua, Jianwu Wang
Rok vydání:	2010
Předmět:	Hydrogen bond Stereochemistry Chemistry Intermolecular force Molecular self-assembly Molecule Phosphoramidate General Chemistry Crystal structure Single Crystal Diffraction
Zdroj:	Chinese Journal of Chemistry. 18:764-769
ISSN:	1001-604X
DOI:	10.1002/cjoc.20000180520
Popis:	Two chiral phosporamidates, (R)-(–)-1, 1′-binaphthyl-2, 2′dihydroxy-N- [α-(S)-methylbenzyl] phosphoramidate and (–)-1,1′-biphenyl-2,2′-dihydroxy-N-[α-(S)-methylbenzyl]-phosphoramidate were synthesized. Their crystal structures were determined by X-ray single crystal diffraction analysis. The phosphoramidate molecules are self-associated by intermolecular NH ···O = P hydrogen bonds and aromatic edge to face interactions.
Databáze:	OpenAIRE
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