Stannous Chloride Dihydrate: A Novel and Efficient Catalyst for the Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes

Autor:	Kaveh Khosravi, Davood Azarifar, Fatemeh Soleimanei
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Aqueous solution Stannous Chloride Dihydrate chemistry Organic Chemistry Hydrogen peroxide Efficient catalyst Acetonitrile Catalysis Nuclear chemistry
Zdroj:	Synthesis. 2009:2553-2556
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0029-1217394
Popis:	Ketones and aldehydes undergo facile hydroperoxidation on treatment with aqueous hydrogen peroxide (30%) in the presence of 10 mol% stannous chloride dihydrate in acetonitrile under very mild conditions to afford the corresponding gem-dihydroperoxides in satisfactory yields.
Databáze:	OpenAIRE
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