Adsorption of organic substances with different physicochemical properties

Autor:	N. S. Polyakov, M. L. Gubkina, T. V. Baikova, A. V. Larin
Rok vydání:	1995
Předmět:	Pore size Freon Chemistry General Chemistry Adsorption Freon 13B1 medicine Molecule Physical chemistry Organic chemistry Gas chromatography Porosity Activated carbon medicine.drug
Zdroj:	Russian Chemical Bulletin. 44:424-426
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf00702379
Popis:	The linear regions of the adsorption isotherms of freon 13B1 (CF3Br) on active carbons with different porous structures were studied by gas chromatography at 343–573 K. The Henry's constants were determined, and the isosteric heats of adsorption (Q) were calculated in the region of zero filling. It was established that theQ values for active carbons with different pore size distributions are almost the same and vary within 38–41 kJ mol−1. This coincidence can be explained assuming that the interaction between the adsorbed molecules and the active carbons occurs in the pores whose sizes are comparable with those of the adsorbed molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2d94378bb66550ed14b5676e0e622379 https://doi.org/10.1007/bf00702379 Zobrazit plný text záznamu Full text from SpringerLink