Organoborane-Modified Silica Supports for Olefin Polymerization: Soluble Models for Metallocene Catalyst Deactivation

Autor:	John F. Corrigan, Hoon Kim, Robert A. Metcalfe, David I. Kreller, Nicholas J. Taylor, Jun Tian, Scott Collins
Rok vydání:	2002
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Organic Chemistry Polymer chemistry Olefin polymerization Physical and Theoretical Chemistry Post-metallocene catalyst Silsesquioxane
Zdroj:	Organometallics. 21:1719-1726
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om010284b
Popis:	Treatment of silsesquioxane 1 with 3.3 equiv of the reactive organoboranes 2 [(C6F5)2BX; X = H or Cl] provides the novel, trifunctional organoborane 3, which was characterized by spectroscopic mean...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2d826956df11a4e928d6eb9381735510 https://doi.org/10.1021/om010284b Zobrazit plný text záznamu