Core/clad compositions with high numerical aperture for single-mode fluoride fibres
Autor: | S. Mosso, J. Kraus, Marco Braglia |
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Rok vydání: | 1996 |
Předmět: |
Materials science
business.industry Glass fiber Analytical chemistry Condensed Matter Physics Cladding (fiber optics) Electronic Optical and Magnetic Materials law.invention Numerical aperture chemistry.chemical_compound Optics chemistry law Materials Chemistry Ceramics and Composites Orthorhombic crystal system Crystallization business Fluoride Refractive index Solid solution |
Zdroj: | Journal of Non-Crystalline Solids. 201:237-245 |
ISSN: | 0022-3093 |
DOI: | 10.1016/0022-3093(96)00143-3 |
Popis: | ZBLYALi core glasses modified by the substitution of LiF for BaF 2 or the addition of PbF 2 and cladding glasses of ZBLYAN composition, into which HfF 4 and NaF were substituted, are described and characterised by their thermal glass parameters and refractive index changes. Glasses studied, with T g range from 533 to 573 K, yielded numerical apertures as high as 0.39, if ZBLYALiPb glasses were used as core. Since incorporation of PbF 2 in ZBLYALi glass led to a strong decrease in glass stability, a closer look at the crystallisation behaviour of ZBLYALiPb was taken. Addition of PbF 2 was found to suppress precipitation of LiBaZr 2 F 11 in favour of a (Ba, Pb)ZrF 6 solid solution with orthorhombic structure. |
Databáze: | OpenAIRE |
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