Intra- and intermolecular metallotropic rearrangements in triethyl(acetylacetonato)germane

Autor:	I. D. Kalikhman, P. V. Makerov, V. A. Pestunovich, N. S. Vyazankin, L. I. Belousova
Rok vydání:	1977
Předmět:	chemistry.chemical_compound chemistry Germane Intramolecular force Intermolecular force Atom chemistry.chemical_element Molecule Germanium General Chemistry Photochemistry Carbonyl group Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:887-889
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01108232
Popis:	1. It was established via NMR that triethyl(acetylacetonato)germane is a mixture of the cis- and trans-isomers of triethylgennoxy-2-penten-4-one. The cis-isomer undergoes intramolecular 1,5-rearrangement. 2. cis-trans Transitions were detected in the undiluted triethylgermoxy-2-penten-4-one, which are caused by intermolecular rearrangements via coordination of the germanium atom with the carbonyl group of the adjacent molecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2d43a47622028d20e50b784c16cfea36 https://doi.org/10.1007/bf01108232 Zobrazit plný text záznamu Full text from SpringerLink