Analysis of the optical spectrum of Np(BD4)4 diluted in Zr(BD4)4 and the magnetic properties of Np(BH4)4 and Np(BH3CH3)4
| Autor: | R. H. Banks, K. Rajnak, E. Gamp, Norman M. Edelstein |
|---|---|
| Rok vydání: | 1984 |
| Předmět: |
chemistry.chemical_classification
Absorption spectroscopy Infrared Analytical chemistry General Physics and Astronomy Magnetic susceptibility law.invention chemistry Orbital # reduction law Vibronic spectroscopy Physical and Theoretical Chemistry Electron paramagnetic resonance Inorganic compound Visible spectrum Nuclear chemistry |
| Zdroj: | The Journal of Chemical Physics. 80:5951-5962 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.446675 |
| Popis: | The optical spectrum of Np(BD4)4/Zr(BD4)4 is reported and analyzed. The parameter values obtained are consistent with those for U(BD4)4/Hf(BD4)4. A total of 46 levels were fit with σ=84 cm−1. EPR data on Np(BD4)4/Zr(BD4)4 and Np(BH3CH3)4/Zr(BH3CH3)4 and the magnetic susceptibility of Np(BH3CH3)4 are reported. They could be fit with the eigenvectors from the optical analysis only by the inclusion of orbital reduction factors k=0.885 for Np(BD4)4 and 0.862 for Np(BH3CH3)4. These values indicate greater covalency for the methylborohydride. |
| Databáze: | OpenAIRE |
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