Anisotropic Electrical Conductivity of a Single-Crystalline Oxo-Bridged Cr4IIIMo2VI Heterometallic Complex

Autor:	Hee Cheul Choi, Gyeongeun Hyun, Seok Min Yoon, Jin Young Koo, Intek Song, Jongwon Oh
Rok vydání:	2021
Předmět:	Anisotropic conductivity Inorganic Chemistry Metal Crystal chemistry.chemical_compound Crystallography Monomer chemistry Electrical resistivity and conductivity visual_art visual_art.visual_art_medium Molecule Physical and Theoretical Chemistry Anisotropy Single crystal
Zdroj:	Inorganic Chemistry. 60:13262-13268
ISSN:	1520-510X 0020-1669
Popis:	A new oxo-bridged chromium-molybdenum heterometallic complex, O-CrMoHC ([Cr4(MoO4)2O2(OAc)4(DMF)4]·2DMF), was synthesized by using a simple solvothermal reaction. In this complex, the octahedrally coordinated Cr(III) and tetrahedrally coordinated Mo(VI) metal centers are bridged by oxo ligands. O-CrMoHC has in-plane π-conjugation systems, which are interconnected by noncoordinating DMF molecules. The crystals show anisotropic conductivity with respect to the crystal planes, and theoretical calculations were used to study their origins. The O-CrMoHC single crystals exhibited that a relatively high electrical conductivity with an average value of 5.37 × 10-7 S/cm was observed along the [01-1] direction, but the current level was very low along the [100] direction. This is the first report of anisotropic conductivity observed in the single crystal of a monomeric heterometallic complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2cf6f4790d11cc584c73667c9fca2e8c https://doi.org/10.1021/acs.inorgchem.1c01618 Zobrazit plný text záznamu