Olefin insertion in transition metal catalysis

Autor:	Gisela Henrici-Olivé, Salvador Olivé
Rok vydání:	2006
Předmět:	Metal Olefin fiber Transition metal Chemistry visual_art Polymer chemistry Migratory insertion visual_art.visual_art_medium Regioselectivity Homogeneous catalysis Electronic structure Catalysis
Zdroj:	Topics in Current Chemistry ISBN: 9783540079002
DOI:	10.1007/bfb0048499
Popis:	Olefin insertions into transition metal-carbon and transition metal-hydrogen bonds are fundamental reactions in homogeneous catalysis. With unsymmetrically substituted olefins, a remarkable regioselectivity is frequently observed, whereby the orientation of the olefin depends on the metal, the ligands, and the olefin itself. Empirical rules of regioselectivity are given, and interpreted on the base of the electronic structure of the reaction partners.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2ce75d49f60ecc85d9054bae44de6683 https://doi.org/10.1007/bfb0048499 Zobrazit plný text záznamu