Spectroscopic investigations of porous silicon prepared by laser-induced etching of silicon

Autor: H. S. Mavi, Bassam G. Rasheed, K. P. Jain, S. C. Abbi, Amit Shukla
Rok vydání: 2001
Předmět:
Zdroj: Journal of Physics D: Applied Physics. 34:292-298
ISSN: 1361-6463
0022-3727
Popis: Porous silicon was fabricated by using a Nd:YAG laser in a laser-induced etching process. Scanning electron microscopy was used to monitor changes in surface morphology produced during the etching process. Porous silicon samples were subjected to spectroscopic investigations using an argon-ion laser. The first-order Raman line asymmetry was found to decrease with decrease of the incident argon-ion laser excitation photon energy, while the peak position remained unchanged for a given etching time and power density. The photoluminescence spectra exhibits a red shift in peak position and a dramatic decrease in intensity as the incident photon energy was decreased. Both Raman and photoluminescence data were explained using appropriate quantum confinement models involving two-dimensional confinement and Gaussian size distributions of nanocrystallites constituting porous silicon samples. There is reasonable agreement between the results obtained from Raman and photoluminescence spectroscopic investigations of the PS samples.
Databáze: OpenAIRE