Pressure dependence of the reversible hydrolysis of thiazolium salts

Autor:	Claude Balny, I. Heiber, W. Knoche
Rok vydání:	1990
Předmět:	Chemistry fungi Inorganic chemistry Reaction scheme food and beverages Protonation Pressure dependence Condensed Matter Physics Ion chemistry.chemical_compound Hydrolysis Deprotonation High pressure Hydroxide
Zdroj:	High Pressure Research. 6:77-83
ISSN:	1477-2299 0895-7959
DOI:	10.1080/08957959008203199
Popis:	The hydrolysis of thiazolium salts is studied under varying pressures between 0.1 and 85 MPa. Activation and reaction volumes are obtained for different reaction steps. The results confirm the reaction scheme, where the thiazolium cation forms a pseudobase by addition of an hydroxide ion. The pseudobase can be protonated or can form a ring-opened species, which can further be deprotonated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2cc1d20603e5517fd119b303a16eeafb https://doi.org/10.1080/08957959008203199 Zobrazit plný text záznamu