Epoxidation of alkenes by Oxone™ using 2-alkyl-3,4-dihydroisoquinolinium salts as catalysts in ionic liquids

Autor:	Jacob M. Crosthwaite, Tom Welton, Victoria A. Farmer, Jason P. Hallett
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Aqueous solution Alkene Process Chemistry and Technology Inorganic chemistry Catalysis chemistry.chemical_compound Hydrocarbon chemistry Organocatalysis Ionic liquid Organic chemistry Physical and Theoretical Chemistry Acetonitrile Alkyl
Zdroj:	Journal of Molecular Catalysis A: Chemical. 279:148-152
ISSN:	1381-1169
Popis:	A number of ionic liquids have been used as co-solvents for the N-alkyl-3,4-dihyroisoquinoliunium catalyzed epoxidation of alkenes. Water miscible ionic liquids gave systems with similar reactivities to the conventional acetonitrile based systems. Attempts to produce an aqueous/ionic liquid biphasic system that could be used to recycle the catalyst failed due to a lack of phase transfer between the aqueous and ionic liquid phases.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c8c4ff78dc8b778ae39eb649e8ac3e1 https://doi.org/10.1016/j.molcata.2007.06.004 Zobrazit plný text záznamu Full Text from ScienceDirect