Isocyanide addition to MN2(CO)5(Ph2PCH2PPh2)2 and the formation of a four-electron doubly-bridging isocyanide

Autor:	Linda S. Benner, Alan L. Balch
Rok vydání:	1977
Předmět:	Inorganic Chemistry chemistry.chemical_compound Bridging (networking) chemistry Stereochemistry Isocyanide Organic Chemistry Materials Chemistry Electron Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 135:339-343
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)88085-7
Popis:	Summary Addition of RNC (R = p-CH3C6H4, C6H5CH2, or CH3) to Mn2(CO)5(dpm)2 (dpm = Ph2PCH2PPh2) produces Mn2(CO)5(CNR)(dpm)2 with a terminal isocyanide. Heating of this complex produces Mn2(CO)5(dpm)2 (R = CH3 or C6H5CH2) or Mn2(CO)4(CNR)(dpm)2 (R = p-CH3C6H4). The latter probably contains a four-electron doubly-bridging isocyanide ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c5a5d767faa3b43636489c7cc297548 https://doi.org/10.1016/s0022-328x(00)88085-7 Zobrazit plný text záznamu